The “Protective Acid Mantle” — a Modern Legend?

Some cosmetic products claim they “restore the pH of our skin” … and that sounds great, and also very scientific, doesn’t it? Maybe you didn’t even know your skin had a pH; maybe you lived in blissful ignorance, not knowing that your pH could get out of balance… So before you start to feel like your day has been ruined, let us briefly explain what pH is.

The term ‘pH’ refers to an attribute of fluids – it’s a way to measure how acidic or alkaline the fluid might be (note: if lemons are naturally acidic, then bitter lemons are alkaline). So there we encounter the first problem: can we consider our skin to be a liquid? Well, obviously it isn’t. But things aren’t always what they seem…

pH of the skin

Inside cells, there is liquid substance, but the pH of this liquid is kept constant and is not influenced by external / environmental factors. When we’re talking about the pH of our skin, we are in fact talking about the pH of an ultra-thin moist film barrier on top of our skin, a mixture of sweat and sebum. This is commonly known as the “acid mantle” – and it has a pH between 4 and 5.5, which means it is very mildly acidic. In this moist environment, some beneficial bacteria feel at home. The pH of the skin can change slightly depending on the amount and quality of our sweat. This has everything to do with what (and how much) we drink and eat, if we do any sports or other physical activities, and if we’re taking any medicine. A ketogenic diet with a high fat & protein intake can make your sweat more acidic, for example.

Sometimes ‘experts’ claim that our skin has become more acidic over the past 60 years due to consistently eating low quality food. But since the pH value can differ from moment to moment, there is really no way to tell if someone’s general pH level has changed over longer periods of time. If we were to believe these theories, then we might get tricked into thinking there is something wrong with our skin… which might make us buy products to help us fix this (non-)issue.

What damages the acid mantle?

Our skin and its pH level do get affected short-term by using certain cosmetic products – especially soaps and bath foams. These are made of highly alkaline substances that work to eradicate our fatty sebum layer – a process you can compare to cleaning your stove with hardcore kitchen cleaner. Removing this fatty layer can “feel good” because it gives us the impression we are clean. But in fact, we are removing a very important part of our natural protection against disease: fats. This can be noticed by a small rise in the pH of our skin.

Cleaning our skin actually isn’t the best of ideas, as it not only removes fats but also our natural skin flora (good bacteria). These bacteria help to stabilize the pH of the skin, since they produce small amounts of lactic acid.
Alkaline products are to blame, but the point is that these so-called “protective” acidic or “pH neutral” cosmetic products aren’t much better. They also contain detergents that eventually dissolve the sebum. All such cleansing products remove some if not all of that protective barrier, and that makes our skin more vulnerable to adverse reactions to creams, for example, which may contain ingredients that can trigger allergies in people who are already prone to develop them. So instead of helping ourselves, we are rather creating new problems as a consequence of our cleanliness.

***Disclaimer***
That the number of allergies among the population is rising has very complex reasoning to it, involving both our general food intake and our immune system. Neither alkaline nor acidic cosmetic products are specifically to blame for this.

What would I suggest?

In my opinion… the most skin-friendly way to clean would be by rinsing your skin with purified water from a beautiful mountain lake – the way our primal ancestors did ♥ But that wouldn’t remove leftover makeup, would it? So your second best bet might be a pH neutral cleanser, so long as it doesn’t contain any alcohol or strong detergents. But products “restoring our pH” … that’s just a marketing trick, like ‘greenwashing’. They simply don’t exist. Perhaps the best thing a product can do for your skin is to affect your natural pH as little as possible.

Sources:
1. Natural skin surface pH is on average below 5, which is beneficial for its resident flora.
2. Why the pH of Skin and Products Are Crucially Important

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Editor’s Note: This article was originally published in January 2013 and was updated in October 2019 for formatting.
Photo By: Igor Rand, Unsplash
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Ms.Ph.C. Natalia Ramade
Ms.Ph.C. Natalia Ramade
4 years ago

Excuse me, regading What protects the acid mantle? So, your opinion as a “chemist” is that what’s best for your skin is rinsing your skin with purified water from a beautiful mountain? You already answered that in the following sentence which I assume by ‘doesn’t remove leftover makeup’ you also mean it doesn’t remove any contaminants from the environment, etc; not doing that any more is called evolving. But as a chemist trying to give your opinion to people that have no idea about skin chemistry, you can NEVER say “So your second-best thing would be a pH neutral….”: FYI:… Read more »

Justin Thesis Smith
Admin
4 years ago

Dear Ms.Ph.C. Natalia Ramade, Firstly, as the Editor of Amazingy Mag i’d like to thank you for reading this article and offering this constructive criticism, especially considering your academic standing ♡ As written in the “Editor’s Note” at the end after the list of sources, this article was originally published in 2013 by Hanny (( who is no longer writing for us )) and then in 2019 only republished by me with a formatting update to match the rest of the blog, leaving the information therein mostly intact ~ but i would guess that after 8 years of cosmetic evolution… Read more »

Michelle Bohlaender
Michelle Bohlaender
6 years ago

Have been researching ” repairing the acid mantle..” & found this statement which is clearly written “from the heart” & not by a manufacturer of some useless product, as many others have been. Very sorry that you have nit continued to write about this subject. So the credibility of the information is less suspect. But why have you not responded to all the comments? The idea of only using water on your face as we did, perhaps, as children, seems like a good idea but poor food choices & hormonal changes definitely have an effect. Why, do you think, acne… Read more »

Alana Bonnemann
6 years ago

Hi Michelle, Thank you so much for your comment. This article was written quite some time ago by our guest writer Hanny, and all the comments somehow managed to slip under the radar. So thanks for bringing it to my awareness! You’re right, we haven’t written much more about the acid mantle, but we have a bunch on content on here about diet and skin health, and other articles related to acne. Take a look at our Skin/Health Concern Index which you can find at the top left header. In my humble opinion, I don’t think acne is always so… Read more »

Cheis
Cheis
7 years ago

If you wash your face with soap and then splash it with apple cider vinegar, which is acidic, you can shift your skin’s pH towards acidic again or in other words, you help your skin ‘restore’ its natural pH (whatever ph that might be for you) There are certain ingredients in cosmetic products that can influence the skin’s pH (e.g. when you have to apply medication you should wait until your skin is more acidic). So when they say ‘restore’ they just mean that it will drop your skin’s pH. I don’t understand why you claim that this is not… Read more »

Jasmin
10 years ago

Hi. I have a question. What about using cream cleansers occasionally? Like once per week? My skin usually ends up with thick clumps of oil and dead skin cells on it if I don’t wash it properly with products… So I was thinking of gradually decreasing the amount of products I use, to see if it will change composition. Or is this a medical problem? Thanks in advance! 🙂 P.S. My skin is burnt around my face and neck. Sunscreens seem to irritate it. I seem to get burnt weather I wear sunscreen or not. I am very fair skinned.… Read more »

Judy
Judy
10 years ago

Hello. I have acidic skin, but my pH levels are great. Is the outer skin suppose to be acidic?

misty
misty
11 years ago

Hi Hanny, Great article. I have been without really any skin products for a week except water and some lavender oil for sunscreen protection during the day.
question: could swimming in a low chlorine pool disrupt this film on the skin? thanks…

Neil
10 years ago
Reply to  misty

It does. Even tap water has an alkaline PH, due to added chemicals like chlorine. You can use vitamin C water filters which removes chlorine from waters by means of chemical reaction with the ascorbic acid. They’re relatively cheap.

Andrew Illingworth
11 years ago

HI Hanny,

I too only recently found out the benefits of not destroying the face’s acid mantle on a daily basis with alkaline-based products.

I have stopped using anything on my face – well except for moisturiser that is supposedly ‘pH balanced’ – only becuase of the dead skin build up my face gets heavy.

I have heard though if you want your skin to truly repair itself (after years of using acne products), you need to not even wash your face with water for one month …. what your opinion on this?

Steve
Steve
12 years ago

You are so right. I’m 36 and I’ve had acne all my life and as of last week I started researching how skin functions and what sebum is and so forth. I then realized well this sebum is here for a reason and I finally found out what for. For this past week I stopped using all soaps and lotions on my face, ALL products. I then started just using room temperature water at night and the morning to just rub my face and rinse off loose dirt and oil. Thats it. I soon found my skin NO LONGER producing… Read more »

Tara
Tara
9 years ago
Reply to  Steve

I’m aware this is waay late, but I agree wholeheartedly with the message of the article! I don’t however entirely agree that we are ‘dumb’ just been bamboozled by ‘Big Pharma’ into not realising that we don’t *need* cleansers, exfoliators, toners, serums, moisturizers even foundation, etc. Along with other products as you’ve already been caught (manipulated, really) into a vicious circle where stripping the skin of its acid mantle by washing with harsh alkaline soaps and cleansers leaves the skin open to pathogenic bacteria, causing issues like acne , to spend more money on lots of make up to cover… Read more »

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